5. Angelina Jolie: Long before Brangelina came into existence, Angelina Jolie was Mrs. Jonny Lee Miller. Jolie and Miller tied the knot in 1996 and separated 18 months later. Their divorce was finalized in 1999 and in early 2000, Jolie won an Oscar for Girl, Interrupted. Jolie went on to become an action icon in 2001 when she was cast as the titular character in Lara Croft: Tomb Raider. Needless to say, things have only gone uphill for the actress and humanitarian.
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