6. Matthew Mcconaughey and Kate Hudson (How To Lose a Guy in 10 Days '03, Fool's Gold '08) - There's something about Matthew. He was tailor-made for a roguish leading man. But there's something about Kate too. The actress brings her exuberant personality to her cute, peppy heroines. Drop these two in the same a rom-com, and we'll easily fall in love. How To Lose A Guy in 10 Days pinned these two against one another, as Kate's journalist Andie attempts to drive away Matthew's Benjamin in a mere ten days for a magazine article, while his goal is to make her fall for him in the same amount of time. It's their best film together. It's cute, fun and hilarious, just like the stars--everything a rom-com should be.