New Couple Alert: January Jones And Jeremy Piven

Although Mad Men's January Jones took her dad to Sunday night's Golden Globes (awwww), she was spotted leaving the Chateau Marmont after-party with Entourage star Jeremy Piven. The two were looking very cozy, walking arm in arm, but went separate ways when they spotted the paps. Could they have hooked up later? 11 Love Lessons From Entourage

Obviously, loudmouth agent Ari Gold and repressed housewife Betty Draper would never get together in a million years, but is an offscreen pairing between those characters' portrayers any less odd? After dating nice guys like Ashton Kutcher and Josh Groban, would the elegant actress really fall for Piven the player? He seems to be with a different girl every time we turn around. And back in March, actress/model Simona Fusco claimed Jeremy was "the date from hell." If her story is to be believed, Jeremy took her out and tried to get her drunk on sake (ostensibly so he could have his way with her) and then got angry when he realized she wasn't going to have sex with him. Of the actor's rep, she said, "I heard around town that he was with this girl and that girl and that he picks up all these girls on set. But that’s gross. I didn’t want to be one of those girls. But I still went out with him because I was curious. However, there was no interesting conversation." 4 First-Date Conversation Killers

Maybe January wants to be "one of those girls?" Or maybe she and Jeremy are just friends who happened to be leaving the same place at the same time? It's a little too early to tell, but we'll be keeping our eye on these two!

Scoop via Celebrity Smack. Photos via SJC/Fame Pictures, Juan Rico/Fame Pictures.